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Time scales for drainage and imbibition in gellified foams: application to decontamination processes

Deleurence , Rémi ; Saison , Tamar ; Lequeux , François ; Monteux , Cécile ; Sciences et Ingénierie de la Matière Molle ( SIMM ) ; Université Pierre et Marie Curie - Paris 6 ( UPMC ) -ESPCI ParisTech-PSL Research University ( PSL ) -Centre National de la Recherche Scientifique ( CNRS ) ; Saint-Gobain Recherche ( SGR ) ; SAINT-GOBAIN

ISSN: 1744-683X

HAL CCSD;Royal Society of Chemistry, 2015

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  • Titre:
    Time scales for drainage and imbibition in gellified foams: application to decontamination processes
  • Auteur: Deleurence , Rémi ;
    Saison , Tamar ;
    Lequeux , François ;
    Monteux , Cécile
  • Autre(s) auteur(s): Sciences et Ingénierie de la Matière Molle ( SIMM ) ; Université Pierre et Marie Curie - Paris 6 ( UPMC ) -ESPCI ParisTech-PSL Research University ( PSL ) -Centre National de la Recherche Scientifique ( CNRS ) ;
    Saint-Gobain Recherche ( SGR ) ; SAINT-GOBAIN
  • Sujets: [ PHYS.COND.CM-SCM ] Physics [physics]/Condensed Matter [cond-mat]/Soft Condensed Matter [cond-mat.soft]
  • Fait partie de: ISSN: 1744-683X
  • Description: International audience
    We probe the drainage and imbibition dynamics of foams in which the continuous aqueous phase is a transient gel-like network. To produce these foams, we provide a new method – a PVA (polyvinyl alcohol) solution is first foamed and then a cross-linker, Borax, is added, which binds reversibly to the PVA chains. The resulting foams are ultra-stable-over a month. We find that the typical time for gravitational drainage of the continuous phase can be slowed down from hours to several weeks by tuning the Borax concentration. We show that the Borax concentration controls both the bulk viscosity of the continuous phase and the surface viscosity of the air–water interfaces. From these results we suggest that the PVA molecules adsorbed at the bubble interfaces are highly cross-linked by the Borax molecules. We find that the capillary rise of a dyed liquid into these foams is orders of magnitude faster than the drainage flow, meaning that these foams can quickly absorb liquids. These results show that these foams could be used to clean or decontaminate surfaces covered with liquid wastes. Indeed we show that the PVA–Borax foam can easily be spread on a surface, absorb a liquid without destabilizing and be dried afterward to recover the waste
  • Titres liés: info:eu-repo/semantics/altIdentifier/doi/ 10.1039/c5sm01158b
  • Éditeur: HAL CCSD;Royal Society of Chemistry
  • Date de publication: 2015
  • Langue: Anglais
  • Identifiant: HAL Id hal--01472976 ; DOI : 10.1039/c5sm01158b
  • Source: ESPCI Paris (archives ouvertes)

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